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Statistical Associating Fluid Theory Coupled with Restricted Primitive Model to Represent Aqueous Strong Electrolytes

by: Sugata P. Tan, Hertanto Adiharma, Maciej Radosz

(Industrial and Engineering Chemistry Research 2005, vol. 44, pp. 4442-4452)

Abstract

Statistical Associating Fluid Theory coupled with Restricted Primitive Model (SAFT1-RPM) represents the mean ionic activity coefficient, density, osmotic coefficient, and va-por pressure of several aqueous alkali halide solutions, in a framework that is analogous to the non-electrolyte framework. SAFT1 alone represents pure water, including the den-sity anomaly. Each SAFT1 salt molecule consists of two segments: cation and anion.